发明名称 |
Hydrogenation of aromatics and other unsaturated organic compounds |
摘要 |
The present invention relates to supported Ni-catalysts optionally comprising Zn as a promoter, methods for the production of said catalysts and uses of said catalysts for the hydrogenation of a hydrocarbon feed. |
申请公布号 |
US8822368(B2) |
申请公布日期 |
2014.09.02 |
申请号 |
US201013319215 |
申请日期 |
2010.05.07 |
申请人 |
Shell Oil Company |
发明人 |
Geyer Reinhard;Hoheisel Klaus;Vander Hoogerstraete Patrick;Hunold Jürgen;Keck Michael;Lose Dirk;Schödel Rainer |
分类号 |
B01J23/755;B01J21/04;B01J21/16;B01J21/06;C07C5/10;B01J35/00;B01J35/10;B01J37/02;B01J23/80;B01J21/12;B01J37/18;B01J37/14 |
主分类号 |
B01J23/755 |
代理机构 |
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代理人 |
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主权项 |
1. A nickel (Ni)-catalyst comprising a support and Ni, wherein the size distribution of the Ni crystallites is bimodal with 30 to 70% of the Ni crystallites having an average size (diameter) in the range of from 1.0 to 2.5 nm and the remaining Ni crystallites having an average size (diameter) in the range of from 3.0 to 4.5 nm, and wherein the Ni is distributed in an outer shell region of the catalyst and a remaining centre of the catalyst in a concentration ratio in the range of from 3.0:1 to 1.3:1, the outer shell region of the catalyst having a penetration depth of 3 to 15% of the catalyst diameter. |
地址 |
Houston TX US |