发明名称 PROCESS FOR HETEROGENEOUSLY CATALYZED PARTIAL GAS PHASE OXIDATION OF PROPYLENE TO FORM ACRYLIC ACID
摘要 PROBLEM TO BE SOLVED: To provide a process for heterogeneously catalyzed partial gas phase oxidation of propylene to form acrylic acid in the presence of propane as an inert diluent gas.SOLUTION: A starting reaction gas mixture comprising propylene, molecular oxygen, and inert diluent gas propane with a molar O2:C3H6 ratio of 1 or greater is conducted through at least one first catalyst bed whose catalysts have at least one multimetal oxide comprising Mo, Fe and Bi, and a product gas mixture is made with the byproduct cyclopropane content of 3 mol% or less based on the molar amount of propane contained in the starting reaction gas mixture 1, to proceed to a further reaction.
申请公布号 JP2014148500(A) 申请公布日期 2014.08.21
申请号 JP20130251949 申请日期 2013.12.05
申请人 BASF SE 发明人 DIETERLE MARTIN;DIEFENBACHER ARMIN;MULLER-ENGEL KLAUS JOACHIM;JOCHEN PETZOLDT
分类号 C07C51/25;B01J23/88;C07B61/00;C07C57/05;C07C67/08;C07C69/54 主分类号 C07C51/25
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