发明名称 |
VALUABLE METAL EXTRACTION AGENT AND VALUABLE METAL EXTRACTION METHOD USING SAID EXTRACTION AGENT |
摘要 |
The objective of the present invention is to selectively extract light rare earth metals, and by extension, europium, from an acidic solution containing a plurality of types of rare earth metal. This valuable metal extraction agent is represented by the general formula. In the formula: R1 and R2 each indicate the same or different alkyl group; R3 indicates a hydrogen atom or an alkyl group; and R4 indicates a hydrogen atom or any given group other than an amino group bonded to the α carbon as an amino acid. Preferably, the general formula has a glycine unit, a histidine unit, a lysine unit, an aspartic acid unit, or an N-methylglycine unit. Preferably, when extracting europium using the extraction agent, the pH is adjusted into the range of 2.0-3.0 inclusive, and when selectively extracting light rare earth metals, the pH is adjusted to 1.7-2.7 inclusive.; |
申请公布号 |
US2014234187(A1) |
申请公布日期 |
2014.08.21 |
申请号 |
US201214001832 |
申请日期 |
2012.11.02 |
申请人 |
Kyushu University, National University Corporation ;SUMITOMO METAL MINING CO., LTD. |
发明人 |
Goto Masahiro;Kubota Fukiko;Baba Yuzo |
分类号 |
C22B59/00;C07C237/06 |
主分类号 |
C22B59/00 |
代理机构 |
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代理人 |
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主权项 |
1. An extraction agent for europium or light rare earths, comprising an amide derivative represented by the following general formula (I):(wherein, R1 and R2 each represent the same or different alkyl groups;
the alkyl group is optionally a straight chain or a branched chain; R3 represents a hydrogen atom or an alkyl group; and R4 represents a hydrogen atom or any group other than an amino group, which is bound to the α carbon as an amino acid). |
地址 |
Fukuoka-shi, Fukuoka JP |