发明名称 |
Method for producing aromatic amines |
摘要 |
The invention relates to a process for preparing aromatic amines by catalytically hydrogenating the corresponding aromatic nitro compound, which comprises using a copper catalyst with a support comprising SiO2, the SiO2 having been prepared by wet grinding and subsequent spray drying. |
申请公布号 |
US8809588(B2) |
申请公布日期 |
2014.08.19 |
申请号 |
US201013320384 |
申请日期 |
2010.05.05 |
申请人 |
BASF SE |
发明人 |
Konigsmann Lucia;Schwab Ekkehard;Hesse Michael;Schneider Christian;Heidemann Thomas;Liekens Celine;Bickelhaupt Jutta;Theis Dirk |
分类号 |
C07C209/00 |
主分类号 |
C07C209/00 |
代理机构 |
Oblon, Spivak, McClelland, Maier & Neustadt, L.L.P. |
代理人 |
Oblon, Spivak, McClelland, Maier & Neustadt, L.L.P. |
主权项 |
1. A process for preparing an aromatic amine, comprising:
hydrogenating, with a copper catalyst, a corresponding aromatic nitro compound, wherein: the copper catalyst comprises a support comprising SiO2 obtained by wet grinding and subsequent spray drying, the copper catalyst additionally comprises potassium and zinc, the copper catalyst has a surface area of from 150 to 380 m2/g, the SiO2 has a surface area of from 400 to 620 m2/g, the hydrogenating is performed at a pressure of 2 to 20 bar and a temperature of 200 to 300° C., the catalyst comprises copper in an amount of 15 to 40% by weight, and the sum of the potassium and zinc and any additional metals present in the copper catalyst is 1 to 10% by weight. |
地址 |
Ludwigshafen DE |