METALLOPORPHYRIN COMPLEX, MANUFACTURING PROCESS THEREFOR AND CARBON DIOXIDE FIXATION CATALYST THEREFROM, AS WELL AS PROCESS FOR MANUFACTURING CYCLIC CARBONATE

摘要

There is provided a metalloporphyrin complex represented by general formula (1):;wherein M is a metal; A1 to A4 are independently of each other a substituent represented by general formula (2):;-D-E+X−  (2)wherein D is a divalent organic group having 1 to 20 carbon atoms; E+ is a quaternary ammonium group or quaternary phosphonium group having 3 to 60 carbon atoms; and X is a halogen atom. There is thus provided a metalloporphyrin complex which, when used as a carbon dioxide fixation catalyst, exhibits high catalytic activity, has a small environmental burden and can be easily synthesized.

主权项

1. A metalloporphyrin complex represented by general formula (1): wherein M is metal; A1 to A4 are independently of each other a substituent represented by general formula (2):
-D-E+X−  (2) wherein D is a divalent organic group having 1 to 20 carbon atoms; E+ is a quaternary ammonium group or quaternary phosphonium group having 3 to 60 carbon atoms; and X is a halogen atom.