| 摘要 |
A resinous composition suitable for use in solution as adhesives for bonding wood to wood, glass, metals and bristles, e.g. for use in paint brushes comprises one part of a polyepoxide which is liquid or has a softening-point below 40 DEG C. and 2/3 -3 parts of a resinous epoxide having a softening point between 40 DEG and 65 DEG C., said resinous epoxide being prepared by reaction of an epihalogen, a polyhydric phenol and an alkali. The low melting-point epoxide is preferably a simple aliphatic polyepoxide, e.g. butane dioxide, bis-(2,3-epoxy propyl) ether (diglycid ether) isoprene dioxide, hexadiene dioxides, limonene dioxide. Complex aliphatic polyepoxides may also be used which are prepared by reaction of an epihalohydrin with a polyhydric alcohol followed by dehydrohalogenation of the product formed. The resinous polyepoxides of higher softening point are preferably prepared by reacting bis phenol with epichlorhydrin in presence of alkali at temperatures of 80-110 DEG C. and washing the product to free it from alkali. The mixed epoxides are preferably used in admixture with phenols, e.g. phenol, cresols, resorcinol, hydroquinone, catechol, bis-phenols and hardening of the mixture is accelerated by the incorporation of a catalyst, e.g. alkalihydroxides or phenoxides, partial esters of phosphoric acid, polyfunctional aliphatic amines, e.g. diethylene triamine or triethylene tetramine, Friedel-Craft type catalysts and complexes thereof with ethers, acid anhydrides, amines, amides, sulphides or diazonium salts. Compositions with or without admixture of phenols may be stored for several days at temperatures below 20 DEG C. in absence of a catalyst and below 40 DEG C. in presence of a catalyst. Polymerization inhibitors may be added to the mixture, e.g. small quantities of organic acids, e.g. oxalic acid. Tables giving the preferred proportions in which the components of the compositions are to be mixed and the viscosity of the compositions thus obtained are given in the Specification. A typical composition is 45 parts liquid epoxide, 40 parts resinous epoxide, 115 parts bis-phenol and 0.1 per cent oxalic acid and is converted to the infusible state by addition of 2 per cent KOH in 50 per cent aqueous solution.
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