发明名称 Lithium-containing complex oxide, non-aqueous secondary battery using the lithium-containing complex oxide, and method for producing the lithium-containing complex oxide
摘要 Because of the composition represented by General Formula: Li1+x+αNi(1−x−y+δ)/2Mn(1−x−y−δ)/2MyO2 (where 0≦x≦0.05, −0.05≦x+α≦0.05, 0≦y≦0.4; −0.1≦δ≦0.1 (when 0≦y≦0.2) or −0.24≦δ≦0.24 (when 0.2<y≦0.4); and M is at least one element selected from the group consisting of Ti, Cr, Fe, Co, Cu, Zn, Al, Ge and Sn), a high-density lithium-containing complex oxide with high stability of a layered crystal structure and excellent reversibility of charging/discharging can be provided, and a high-capacity non-aqueous secondary battery excellent in durability is realized by using such an oxide for a positive electrode.
申请公布号 US8801960(B2) 申请公布日期 2014.08.12
申请号 US200812023704 申请日期 2008.01.31
申请人 Hitachi Maxell, Ltd. 发明人 Ueda Atsushi;Uchitomi Kazutaka;Aoyama Shigeo
分类号 H01M4/48;H01M4/50;H01M4/52 主分类号 H01M4/48
代理机构 Osha Liang LLP 代理人 Osha Liang LLP
主权项 1. A method for producing a lithium-containing complex oxide, comprising: coprecipitating a complex compound containing at least Ni and Mn as constituent elements in an inactive atmosphere; mixing the complex compound and a compound of Li at a predetermined ratio; and sintering the mixture at a sintering temperature of about 700° C. to 1100° C. in an atmosphere containing oxygen, thereby forming a complex oxide with a layered crystal structure, wherein the lithium-containing complex oxide further contains a substituent element M, wherein the substituent element M contains Co, and assuming that a total quantity of Ni, Mn, and the substituent element M is 1-x, and a quantity ratio of the substituent element M is y, x satisfies 0≦x≦0.05, y satisfies 0.1<y≦0.4, and a quantity ratio of Co is 0.1 or more, wherein a composition of the complex compound containing at least Ni and Mn as constituent elements is adjusted so that a difference δ in a quantity ratio between Ni and Mn constituting the lithium-containing complex oxide satisfies −0.1≦δ≦0.1, and wherein an average valence of Mn constituting the lithium-containing complex oxide is set to be about 3.3 to 4.
地址 Osaka JP