发明名称 |
Lithium-containing complex oxide, non-aqueous secondary battery using the lithium-containing complex oxide, and method for producing the lithium-containing complex oxide |
摘要 |
Because of the composition represented by General Formula: Li1+x+αNi(1−x−y+δ)/2Mn(1−x−y−δ)/2MyO2 (where 0≦x≦0.05, −0.05≦x+α≦0.05, 0≦y≦0.4; −0.1≦δ≦0.1 (when 0≦y≦0.2) or −0.24≦δ≦0.24 (when 0.2<y≦0.4); and M is at least one element selected from the group consisting of Ti, Cr, Fe, Co, Cu, Zn, Al, Ge and Sn), a high-density lithium-containing complex oxide with high stability of a layered crystal structure and excellent reversibility of charging/discharging can be provided, and a high-capacity non-aqueous secondary battery excellent in durability is realized by using such an oxide for a positive electrode. |
申请公布号 |
US8801960(B2) |
申请公布日期 |
2014.08.12 |
申请号 |
US200812023704 |
申请日期 |
2008.01.31 |
申请人 |
Hitachi Maxell, Ltd. |
发明人 |
Ueda Atsushi;Uchitomi Kazutaka;Aoyama Shigeo |
分类号 |
H01M4/48;H01M4/50;H01M4/52 |
主分类号 |
H01M4/48 |
代理机构 |
Osha Liang LLP |
代理人 |
Osha Liang LLP |
主权项 |
1. A method for producing a lithium-containing complex oxide, comprising:
coprecipitating a complex compound containing at least Ni and Mn as constituent elements in an inactive atmosphere; mixing the complex compound and a compound of Li at a predetermined ratio; and sintering the mixture at a sintering temperature of about 700° C. to 1100° C. in an atmosphere containing oxygen, thereby forming a complex oxide with a layered crystal structure, wherein the lithium-containing complex oxide further contains a substituent element M, wherein the substituent element M contains Co, and assuming that a total quantity of Ni, Mn, and the substituent element M is 1-x, and a quantity ratio of the substituent element M is y, x satisfies 0≦x≦0.05, y satisfies 0.1<y≦0.4, and a quantity ratio of Co is 0.1 or more, wherein a composition of the complex compound containing at least Ni and Mn as constituent elements is adjusted so that a difference δ in a quantity ratio between Ni and Mn constituting the lithium-containing complex oxide satisfies −0.1≦δ≦0.1, and wherein an average valence of Mn constituting the lithium-containing complex oxide is set to be about 3.3 to 4. |
地址 |
Osaka JP |