发明名称 METHOD OF PRODUCING CATALYST FOR POLYMERISATION OF LACTONES OR POLYCONDENSATION OF ALPHA-OXYACIDS
摘要 FIELD: chemistry.SUBSTANCE: disclosed is a method of producing a catalyst by reacting tin metal with oxyacids, wherein catalyst synthesis is carried out in a melt or solution of oxyacids in the presence of oxidising agents at temperature of 20-240°C while stirring constantly. The oxidising agents used are air or molecular oxygen or hydrogen peroxide or organic hydroperoxides. The ?-oxyacids used are compounds with ratio of hydroxyl to carboxyl groups in the range of 1(3):3(1). Condensation of oxyacids with removal of the released water can be carried out concurrently or consecutively with catalyst synthesis.EFFECT: simple process of producing a catalyst which is compatible with the next catalysis objects, is protected from hydrolysis and does not require solvent for dosage.4 cl, 1 tbl, 11 ex
申请公布号 RU2525235(C1) 申请公布日期 2014.08.10
申请号 RU20130122939 申请日期 2013.05.20
申请人 FEDERAL'NOE GOSUDARSTVENNOE BJUDZHETNOE UCHREZHDENIE "NATSIONAL'NYJ ISSLEDOVATEL'SKIJ TSENTR "KURCHATOVSKIJ INSTITUT" 发明人 POLJAKOV DMITRIJ KONSTANTINOVICH;KIRJUKHIN JURIJ IVANOVICH;SEDUSH NIKITA GENNAD'EVICH;GRIGOR'EV TIMOFEJ EVGEN'EVICH;CHVALUN SERGEJ NIKOLAEVICH
分类号 B01J37/12;B01J23/14;B01J31/12;B01J37/14;C07F7/22;C08G63/85 主分类号 B01J37/12
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