Silicone resin, process for producing the same, and curable resin composition comprising the same

摘要

Provided are a silicone resin that yields a cured product excellent in flexibility, toughness, and heat resistance and high in transparency, a process for producing the said silicone resin, and a curable resin composition comprising the said silicone resin. The silicone resin is obtained by reacting an organopolysiloxane containing SiH groups represented by general formula (3) with an organopolysiloxane containing hydroxyl groups at both ends represented by general formula (5) and an alcohol containing radically reactive groups represented by general formula (6) in the presence of a hydroxylamine compound represented by general formula (4) as a catalyst and this silicone resin is used in formulating a curable resin composition. In the general formulas, R is an alkyl group of 1-12 carbon atoms optionally containing an oxygen atom or an aryl group, R1 is an alkyl group, Y is a hydrocarbon group of 1-12 carbon atoms optionally containing an oxygen atom, Z is a (meth)acryloyl group, a vinyl group, or an allyl group, and n, s, m, and r are numbers respectively expressed as 0

主权项

1. A process for producing a silicone resin containing radically reactive groups which comprises reacting an organopolysiloxane containing SiH groups represented by the following general formula (3) wherein R is an alkyl group of 1-12 carbon atoms optionally containing an oxygen atom or an aryl group, and s and in are numbers respectively expressed as 0HONR12  (4) wherein R1 is an alkyl group, with an organopolysiloxane containing hydroxyl groups at both ends represented by the following general formula (5) wherein R is an alkyl group of 1-12 carbon atoms optionally containing an oxygen atom or an aryl group, and n is a number expressed as 0HO(Y)(Z)r  (6) wherein Y is a hydrocarbon group of 1-12 carbon atoms optionally containing an oxygen atom, Z is a (meth)acryloyl group, a vinyl group, or an ally group, and r is a number expressed as 1≦r≦6.