| 主权项 |
1. A hydrocarbon conversion process comprising contacting a stream comprising at least one hydrocarbon with a catalyst at hydrocarbon conversion conditions to generate at least one converted product, wherein the catalyst is a microporous crystalline MAPSO-64M material comprising a three-dimensional framework of EO2−, PO2+, [M2+O2]2− and SiO2 tetrahedral units the composition given by the empirical formula:
M′np+Mm2+EPxSiyOz where M is at least one metal cation of valence +2 selected from the group consisting of Be2+, Mg2+, Zn2+, Co2+, Mn2+, Fe2+, Ni2+, “m” is the mole ratio of M to E and varies from 0 to about 1.5, M′ is selected from the group consisting of NH4+, H+, alkali metals, alkaline earth metals, rare earth metals, and mixtures thereof, “n” is the mole ratio of M′ to E and has a value of about 0.03 to about 2.0, “p” is the weighted average valence of M′, E is an trivalent element selected from the group consisting of aluminum, gallium, iron, boron and mixtures thereof, “x” is mole ratio of P to E and varies from 0.5 to about 2.5, “y” is the mole ratio of Si to E and varies from 0.01 to about 1.0 and “z” is the mole ratio of 0 to E and has a value determined by the equation:
z=(p·n+2·m+3+5·x+4·y)/2and is characterized in that it has the x-ray diffraction pattern having at least the d-spacings and intensities set forth in Table A:TABLE A2Θd (Å)I/I06.81-6.6112.98-13.34m-vs7.75-7.5511.40-11.70m-vs13.36-13.146.62-6.73w-m13.51-13.326.55-6.64w-m14.98-14.685.91-6.03w15.51-15.345.71-5.77w-m18.99-18.794.67-4.72w-m20.26-20.074.38-4.42w-m21.50-21.244.13-4.18w-s24.10-23.843.69-3.73w-m24.30-24.033.66-3.70w-m24.57-24.233.62-3.67w-m26.83-26.513.32-3.36w-m27.59-27.423.23-3.25w-m27.86-27.593.20-3.23w28.68-28.493.11-3.13w28.87-28.593.09-3.12w30.06-29.762.97-3.00w-m30.27-29.962.95-2.98w-m31.03-30.702.88-2.91w-m33.80-33.542.65-2.67w-m34.06-33.802.63-2.65w35.60-35.312.52-2.54w-m36.65-36.342.45-2.47w38.44-38.102.34-2.36wand the microporous crystalline MAPSO-64C material comprises a three-dimensional framework of EO2−, PO2+, SiO2 and [M2+O2]2− tetrahedral units characterized by the empirical formula:
HaMm2+EPxSiyOz where M is at least one metal cation of valence +2 selected from the group consisting of Be2+, Mg2+, Zn2+, Co2+, Mn2+, Fe2+, Ni2+, “m” is the mole ratio of M to E and varies from 0.01 to about 1.5, H is a proton, “a” is the mole ratio of H to E and has a value of about 0.1 to about 2.0, E is an trivalent element selected from the group consisting of aluminum, gallium, iron, boron and mixtures thereof, “x” is mole ratio of P to E and varies from 0.5 to about 2.5, “y” is the mole ratio of Si to E and varies from 0.01 to about 1.0 and “z” is the mole ratio of 0 to E and has a value determined by the equation:
z=(a+2·m+3+5·x+4·y)/2.wherein the hydrocarbon conversion process is selected from the group consisting of cracking, alkylation, isomerization, polymerization, reforming, hydrogenation, dehydrogenation, transalkylation, dealkylation, hydration, dehydration, hydrofining, hydrodenitrogenation, hydrodesulfurization, methanol to olefins, methanation, syngas shift process, olefin dimerization, oligomerization, dewaxing, and combinations thereof. |
