发明名称 |
METHOD OF CATALYTIC METHANE OXYCHLORINATION |
摘要 |
FIELD: chemistry.SUBSTANCE: invention relates to a method of catalytic methane oxychlorination in a deck-type adiabatic reactor under pressure of 1-10 atm in presence of a catalyst, which contains on a porous carrier with a specific surface of 1-60 m/g a mixture of copper, potassium and lanthanum chlorides in a molar ratio of 1:1:0.3 in an amount of 3-30 wt % of the carrier weight and distributed on each reactor deck by 30% higher than the previous one. The two-layered catalyst in the form of equal in volume layers is loaded into the deck-type adiabatic reactor by a flow of reaction gas on each deck of the adiabatic reactor, the first layer of the catalyst contains a mixture of copper, potassium and lanthanum chlorides in a molar ratio of 1:1:0.3, and the second layer of the catalyst - a mixture of copper and potassium chlorides in a molar ratio of 1:1.EFFECT: conversion of hydrogen chloride remains stable when the claimed method is applied.1 ex, 1 tbl |
申请公布号 |
RU2522575(C1) |
申请公布日期 |
2014.07.20 |
申请号 |
RU20130111924 |
申请日期 |
2013.03.18 |
申请人 |
OBSHCHESTVO S OGRANICHENNOJ OTVETSTVENNOST'JU "NAUCHNO-ISSLEDOVATEL'SKIJ INZHENERNYJ TSENTR "SINTEZ" (OOO NIITS "SINTEZ");ASSOTSIATSIJA DELOVOGO SOTRUDNICHESTVA V OBLASTI PEREDOVYKH KOMPLEKSNYKH TEKHNOLOGIJ "ASPEKT" |
发明人 |
TREGER JURIJ ANISIMOVICH;ROZANOV VJACHESLAV NIKOLAEVICH;TRUSOV LEV IL'ICH;MURASHOVA OL'GA PETROVNA;JAS'KOVA VERA JAKOVLEVNA;SILINA IRINA SERGEEVNA |
分类号 |
C07C19/03;C07C1/26;C07C11/04;C07C11/06;C07C17/154 |
主分类号 |
C07C19/03 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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