发明名称 METHOD OF MANUFACTURING POLYMER ION-EXCHANGE MEMBRANE BY RADIATION-CHEMICAL METHOD
摘要 FIELD: chemistry.SUBSTANCE: polymer matrix, which is in a solution of one or several monomers from the group of unsaturated cyclic hydrocarbons, is irradiated by ions with energy, sufficient for ion passing through a polymer matrix material. Ion density is selected such that the solution temperature does not reach its boiling temperature in the process of irradiation. After that, the polymer matrix, which is in a monomer solution, is placed into an ultrasonic bath, filled with liquid, and subjected to the impact of ultrasound. In case of necessity under impact of an ultrasound process of sulphonation or phosphatisation of graft monomers is carried out. In both cases ultrasound has a frequency in the range from 2·10to 10Hz and intensity of sound radiation not less than 0.2 W/cm.EFFECT: invention makes it possible to increase ion-exchange capacity of a membrane, reduce the time of its obtaining.2 ex
申请公布号 RU2523464(C2) 申请公布日期 2014.07.20
申请号 RU20120144965 申请日期 2012.10.22
申请人 FEDERAL'NOE GOSUDARSTVENNOE BJUDZHETNOE OBRAZOVATEL'NOE UCHREZHDENIE VYSSHEGO PROFESSIONAL'NOGO OBRAZOVANIJA "NATSIONAL'NYJ ISSLEDOVATEL'SKIJ TOMSKIJPOLITEKHNICHESKIJ UNIVERSITET" 发明人 GOLOVKOV VLADIMIR MIKHAJLOVICH;SOKHOREVA VALENTINA VIKTOROVNA;TJURIN JURIJ IVANOVICH;SIGFUSSONN TORSTEINN INGI
分类号 C08F2/46;B01D67/00;C08J5/22 主分类号 C08F2/46
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