发明名称 Process for the manufacture of 2-chloro-3,3,3-trifluoropropene (HFCO 1233xf) by liquid phase fluorination of pentachloropropane
摘要 Process of catalytic fluorination in liquid phase of product 1,1,1,2,3-pentachloropropane or/and 1,1,2,2,3-pentachloropropane into product 2-chloro-3,3,3-trifluoropropene in presence of a catalyst.
申请公布号 US8779218(B2) 申请公布日期 2014.07.15
申请号 US201113642589 申请日期 2011.03.21
申请人 Arkema France 发明人 Pigamo Anne;Wendlinger Laurent;Bonnet Philippe
分类号 C07C17/23;C07C17/25 主分类号 C07C17/23
代理机构 Brinks Gilson & Lione 代理人 Brinks Gilson & Lione
主权项 1. A process for preparing 2-chloro-3,3,3-trifluoropropene comprising fluorinating in a liquid phase in an organic medium a reactant comprising 1,1,1,2,3-pentachloropropane or/and 1,1,2,2,3-pentachloropropane in the presence of a catalyst, wherein the organic medium is selected from the group consisting of 1,2-dichloroethane, 1,2,3-trichloropropane, 1-chloro-1-fluoroethane, 1,1-difluoroethane, 1,1-dichloro ethane and 1,3-dichloro-1-fluorobutane, tetrachlorofluoropropane isomers, trichlorodifluoropropane isomers and dichlorotrifluoropropane isomers, 1,1,1,3,3-pentafluorobutane and 1,1,2-trichloro-2,2-difluoroethane, nitrated solvents including nitromethane and nitrobenzene, sulfones including tetramethylene sulfone and dimethyl sulfone, 1,1,2-trichloro-2-fluoroethane, perchloroethylene, and mixtures thereof.
地址 Colombes FR