发明名称 |
Methods for electrochemically induced cathodic deposition of crystalline metal-organic frameworks |
摘要 |
Embodiments of the invention relate to a method for preparing crystalline metal-organic frameworks (MOFs). The method includes the steps of providing an electrolyte solution in contact with a conductive surface, and applying a current or potential to the conductive surface in contact with the electrolyte solution. The electrolyte solution includes a protonated organic ligand, a metal ion, and a probase. Application of the reductive current or potential to the conductive surface produces the crystalline metal-organic framework (MOF) deposited on the conductive surface. The MOFs produced by the method may be incorporated into a gas separation membrane, a purification filter, and/or a sensor. |
申请公布号 |
US8764887(B2) |
申请公布日期 |
2014.07.01 |
申请号 |
US201213439355 |
申请日期 |
2012.04.04 |
申请人 |
Massachusetts Institute of Technology |
发明人 |
Dinca Mircea;Li Minyuan |
分类号 |
B01D53/22 |
主分类号 |
B01D53/22 |
代理机构 |
Choate, Hall & Stewart LLP |
代理人 |
Choate, Hall & Stewart LLP |
主权项 |
1. A method for preparing a crystalline metal-organic framework (MOF), the method comprising the steps of:
providing an electrolyte solution in contact with a conductive surface, the electrolyte solution comprising a protonated organic ligand, a metal ion, and a probase; and applying a current or potential to the conductive surface in contact with the electrolyte solution, thereby producing the crystalline metal-organic framework (MOF) deposited on the conductive surface. |
地址 |
Cambridge MA US |