发明名称 Hydrotreating process
摘要 A process for hydrotreating a first aromatics- and sulfur-containing hydrocarbon feed using a fresh supported CoMo catalyst, includes treating the fresh catalyst under first hydrotreating conditions with a second hydrocarbon feed having a lower aromatics content than the first feed.
申请公布号 US8747659(B2) 申请公布日期 2014.06.10
申请号 US20100660249 申请日期 2010.02.23
申请人 ExxonMobil Research and Engineering Company 发明人 Kiss Gabor;Nistor Lulian;Zengel John
分类号 C10G45/00;B01J23/16;B01J23/92;C10G45/08;C10G45/06 主分类号 C10G45/00
代理机构 代理人
主权项 1. A process for hydrotreating a first aromatics- and sulfur-containing hydrocarbon feed boiling in the diesel fuel range using a fresh supported CoMo catalyst, the process comprising: treating a fresh, sulfided CoMo hydrotreating catalyst having a support of amorphous alumina, silica or alumina-silica, under first hydrotreating conditions including a temperature of about 300° C. to about 350° C., a pressure of about 1.5 MPaq to about 3.5 MPaq, and an LHSV of about 0.3 hr−1 to about 1.0 hr−1 with a second hydrocarbon feed having a lower aromatics content than said first feed, the second hydrocarbon feed having an aromatics content of less than 20 wt % to reduce the activity of the catalyst by at least 5% and, following the treatment with the second hydrocarbon feed, hydrotreating the first feed using the treated catalyst under hydrotreating conditions including a temperature of about 300° C. to about 380° C., a pressure of about 1.5 MPag to about 3.5 MPaq, and an LHSV of about 0.2 hr−1 to about 0.8 hr−to reduce the sulfur content of said first feed to 15 wppm or less.
地址 Annandale NJ US