发明名称 Process for the anodic cross-dehydrodimerization of arenes
摘要 The invention relates to a process for preparing biaryls by anodic cross-dehydrodimerization of substituted phenols with arenes in the presence of partially fluorinated and/or perfluorinated mediators and a supporting electrolyte.
申请公布号 US8747646(B2) 申请公布日期 2014.06.10
申请号 US201013375495 申请日期 2010.06.01
申请人 BASF SE 发明人 Fischer Andreas;Malkowsky Itamar Michael;Stecker Florian;Waldvogel Siegfried R.;Kirste Axel
分类号 C25B3/10;C25B3/00;C25B3/02 主分类号 C25B3/10
代理机构 代理人
主权项 1. A process for preparing a biaryl, the process comprising: anodically dehydrodimerizing (a) a substituted aryl alcohol comprising an alcohol group bound directly to an aromatic ring, with (b) an arene, in the presence of at least one mediator selected from the group consisting of a partially fluorinated mediator and a perfluorinated mediator, and a supporting electrolyte, to obtain a cross-coupling product, wherein the arene is a monosubstituted or polysubstituted benzene derivative, monosubstituted or polysubstituted naphthalene derivative, monosubstituted or polysubstituted benzodioxole derivative, monosubstituted or polysubstituted furan derivative, or monosubstituted or polysubstituted indole derivative, and each substituent of the arene is independently selected from the group consisting of methyl, ethyl, n-propyl, isopropyl, n-butyl, trifluoromethyl, fluorine, chlorine, bromine, iodine, methoxy, ethoxy, methylene, ethylene, propylene, isopropylene, benzylidene, amino, nitrile, and nitro.
地址 Ludwigshafen DE