| 摘要 |
A new family of aluminosilicate zeolites designated UZM-44 has been synthesized. These zeolites are represented by the empirical formula.
NanMmk+TtAl1-xExSiyOz
where “n” is the mole ratio of Na to (Al+E), M represents a metal or metals from zinc, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, “m” is the mole ratio of M to (Al+E), “k” is the average charge of the metal or metals M, T is the organic structure directing agent or agents, and E is a framework element such as gallium. These zeolites are similar to IM-5 but are characterized by unique compositions and synthesis procedures and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for carrying out various separations. |
| 主权项 |
1. A hydrocarbon conversion process comprising contacting a hydrocarbon with a catalytic composite at hydrocarbon conversion conditions to give at least one converted product, the catalytic composite comprising a microporous crystalline zeolite, UZM-44-Modified, having a three-dimensional framework of at least AlO2 and SiO2 tetrahedral units and an empirical composition in the hydrogen form expressed by an empirical formula of
M1aN+Al(1-x)ExSiy′Oz″ where M1 is at least one exchangeable cation selected from the group consisting of alkali, alkaline earth metals, rare earth metals, ammonium ion, hydrogen ion and combinations thereof, “a” is the mole ratio of M1 to (Al+E) and varies from about 0.05 to about 50, “N” is the weighted average valence of M1 and has a value of about +1 to about +3, E is an element selected from the group consisting of gallium, iron, boron, and combinations thereof, x is the mole fraction of E and varies from 0 to 1.0, y′ is the mole ratio of Si to (Al+E) and varies from greater than about 9 to virtually pure silica and z″ is the mole ratio of O to (Al+E) and has a value determined by the equation:
z″=(a·N+3+4·y′)/2 and is characterized in that it has the x-ray diffraction pattern having at least the d-spacings and intensities set forth in Table B:TABLE B2-Thetad (†) I/Io %7.7111.47m-s8.8410.00m-s9.249.56 m11.767.52 vw-w12.46 7.10 m14.38 6.15 vw14.64 6.05 w15.26 5.80 w15.52 5.70 w-m16.58 5.34 w17.72 5.00 w-m18.64 4.76 w22.56 3.94 w-m23.06 3.85 vs23.40 3.80 s24.12 3.69m25.06 3.55m26.16 3.40vw-w26.74 3.33w-m28.82 3.10w-m30.12 2.96w35.86 2.50vw-w45.32 2.00w46.05 1.97vw-w46.92 1.93vw-w wherein the hydrocarbon conversion process is hydrocracking or hydrotreating and wherein the hydrocracking or hydrotreating is operated at a temperature in the range of about 400° to about 1200° F. (204-649° C.) and a pressure in the range of atmospheric to about 3,500 psig (24,132 kPa g).
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