发明名称 PARTIALLY FLUORINATED COPOLYMERS
摘要 This invention is directed to a copolymer comprising fluorinated (met)acrylates, alkyl methacrylates, ethoxylates (meth)acrylates, and alkyl amino (meth)acrylates. These copolymers are capable of providing improved oil and water repellency to hard substrates while also maintaining its stability in a mixture of organic solvents.
申请公布号 US2014154420(A1) 申请公布日期 2014.06.05
申请号 US201314071718 申请日期 2013.11.05
申请人 E I DU PONT DE NEMOURS AND COMPANY 发明人 SWOREN JOHN CHRISTOPHER
分类号 C09D133/14 主分类号 C09D133/14
代理机构 代理人
主权项 1. A partially fluorinated copolymer comprising the reaction product of monomers copolymerized in the following percentages by weight: a) from about 45% to about 75% of one or more monomers of Formula (I): Rf-L-Q-C(O)—CR1═CH2  (I); b) from about 25% to about 30% of one or more monomers of Formula (II): RH-Q-C(O)—CR2═CH2  (II); c) from about 0.5% to about 15% of one or more monomers of Formula (III): R—(OCH2CH2)n—(OCH2CH(CH3))pQ-C(O)—CR3═CH2  (III); d) from about 0.1% to about 4% of one or more monomers of Formula (IV): e) from about 0% to about 2% of one or more monomers of Formula (V): HO—C(O)—CR8═CH2  (V); f) from about from about 0% to about 2% of one or more monomers of Formula (VI): HO—CH2CH2-Q-C(O)—CR9═CH2  (VI); g) from about from about 0% to about 2% of one or more monomers of Formula (VII): CH2═CR10C(O)O(CH2CH2O)x(CH2CH(CH3)O)yC(O)CR11═CH2  (VII);wherein Rf is a linear or branch fluoroalkyl of 2 to 10 carbons optionally interrupted by 1 to 4 interrupting groups —O—, —CH2—, and/or —CHF— groups; RH is a linear, branched, or cyclic alkyl chain of 7 to 22 carbons; each Q is independently —O— or —S—; L is —R12—, —SO2—N(R13)—R15—, —CO—N(R14)—R15—, —CH2CH(OR14)CH2—, —R6—SO2—N(R14)—R15—, or —R15—O—C(O)—N(R14)—R15—; R1, R3, R7, R8, R9, R10, R11 are each independently H or —CH3; R is —H or a linear, branched, or cyclic alkyl chain of 1 to 20 carbons; R2 is —CH3; R4 and R5 are each independently methyl or ethyl; R6, R12 and R15 are each independently a linear or branched divalent alkyl chain of 2 to 10 carbons; R13 and R14 are each independently —H, —CH3, C2 to C10 alkylene, or C1 to C4 acyl; n is 0 to 10 and p is 0 to 10 provided that when p is 0, n is at least 2 and n+p is greater than 0; and x is 0 to 10 and y is 0 to 10 provided that x+y is at least 1; wherein the concentration of monomers of a), b), c), d), e), f), and g) is equal to 100% by weight.
地址 Wilmington DE US