发明名称 |
ONE-STEP SYNTHESIS OF BLOCK COPOLYMERS VIA A DUAL INITIATOR ROUTE COMBINING REVERSIBLE ADDITION-FRAGMENTATION CHAIN TRANSFER(RAFT) POLYMERIZATION AND RING-OPENING POLYMERIZATION(ROP) |
摘要 |
The present invention relates to a one-step synthesis method for block copolymers using a bifunctional initiator, wherein the method is in combination with: reversible addition-fragmentation chain transfer polymerization (RAFT) and ring-opening polymerization (ROP); and to the block copolymers produced thereby. Provided is the one-step synthesis method for the block copolymers comprising a step of RAFT of methacrylate monomers and ROP of lactone monomers in the presence of 4-cyano-1-hydroxypent-4-yl dithiobenzoate, which is the bifunctional initiator, and diphenyl phosphate (DPP), which is a catalyst for the ROP. Provided is also the one-step synthesis method for the block copolymers comprising a step of RAFT of vinyl monomers and ROP of cyclic monomers in the presence of 4-cyano-4-(dodecylsulfanylthiocarbonyl)sulfanylpentanol (CDP), which is the bifunctional initiator, and 4-dimethylaminopyridine (DMAP) or diphenyl phosphate (DPP), which is a catalyst for the ROP. |
申请公布号 |
KR20140052589(A) |
申请公布日期 |
2014.05.07 |
申请号 |
KR20120118825 |
申请日期 |
2012.10.25 |
申请人 |
INHA-INDUSTRY PARTNERSHIP INSTITUTE |
发明人 |
YOUK, JI HO;YU, YOUNG CHANG;KANG, HYUN UK;SHIN, SANG JIN |
分类号 |
C08F283/14;C08F2/46;C08F2/50;C08G63/08 |
主分类号 |
C08F283/14 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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