发明名称 ALKYLATION FOR OBTAINING DETERGENTS WITH APPLICATION OF CATALYST SUBJECTED TO EXCHANGE WITH RARE EARTH ELEMENT
摘要 FIELD: chemistry.SUBSTANCE: invention relates to method of obtaining monoalkylated aromatic compound, in which: aromatic raw material and olefin compound are passed into reactor of alkylation, with reactor of alkylation including catalyst, which contains zeolite with molar ratio of silicon dioxide to aluminium oxide being less than 8, and rare earth element, embedded into zeolite lattice; amount of rare earth element constitutes more than 16.5 wt % in terms of zeolite, the remaining part includes cations of alkali, alkali earth elements, nitrogen compounds or their mixtures, rare earth elements are involved into exchange to such a degree that molar ratio of rare earth element to aluminium is within the range 0.51-1.2; the remaining cation-exchange ions are represented by cations, selected from group, consisting of alkali, alkali earth elements, nitrogen compounds or their mixture, thus forming output flow. Output flow is directed to operation of separation, thus forming flow of aromatic compounds, flow of products, containing monoalkylated aromatic compound, and flow of non-productive alkylated aromatic compounds.EFFECT: method makes it possible to increase quality of alkylbenzene by increase of alkylbenzene linearity.9 cl, 1 tbl, 1 dwg
申请公布号 RU2510639(C2) 申请公布日期 2014.04.10
申请号 RU20120128875 申请日期 2010.09.14
申请人 JUOP LLK 发明人 DZHEHN DEHN-JAN;RAJLI MARK DZH.;SON STIVEN V.;MOSKOSO DZHEJMI DZH.;MILLER RAELIN M.
分类号 C07C2/66;B01J23/10;B01J29/08;C07C15/107 主分类号 C07C2/66
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