发明名称 METHODS FOR PRODUCING SILYLAMINE AND AMMONIA
摘要 PROBLEM TO BE SOLVED: To provide a novel method for producing a silylamine, which uses a catalyst comprising an iron complex containing no molybdenum.SOLUTION: There is provided the method for producing a silylamine, which includes forming a silylamine represented by formula N(SiRRR)(In the formula, R, R, and Rare each independently selected from the group consisting of hydrogen and a C- Clinear, branched, or cyclic hydrocarbon group) by reacting a nitrogen gas with a silyl halide represented by formula SiRRRX (In the formula, R, R, and Rare each independently selected from the group consisting of a hydrogen atom and a C- Clinear, branched, or cyclic hydrocarbon group, and X is a halogen atom) in the presence of a catalyst which comprises an iron complex containing iron but not containing molybdenum, and a reducing agent.
申请公布号 JP2014058477(A) 申请公布日期 2014.04.03
申请号 JP20120204420 申请日期 2012.09.18
申请人 TOYOTA MOTOR CORP;UNIV OF TOKYO 发明人 SHIMAZAKI RYUJI;SATO AKINORI;NISHIBAYASHI HITOAKI;YUKI MASAHIRO
分类号 C07F7/10;B01J31/28;C07B61/00;C07F7/08 主分类号 C07F7/10
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