摘要 |
1,142,609. Disproportionation of olefins. PHILLIPS PETROLEUM CO. 15 Nov., 1966 [22 Nov., 1965], No. 51232/66. Addition to 1,006,049. Heading C5E. The disproportionation of C 7-20 olefins is effected in the presence of silica promoted with tungsten oxide or molybdenum oxide. The catalyst may be activated by treatment with CO or H 2 , and may contain MgO. Examples describe the disproportionation of heptene-3 an equilibrium mixture of heptenes-1, 2 and 3, and a mixture of C 7-18 olefins containing predominantly C 10-12 n-olefins. |