| 摘要 |
1,158,270. Polyesterurethanes. BADISCHE ANILIN- & SODA-FABRIK A.G. 2 Dec., 1966 [4 Dec., 1965], No. 54078/66. Heading C3R. Polyesterurethanes are prepared by reacting an hydroxyl group containing polyester of M.W. 500 to 5,000 which has been prepared by reacting adipic acid with a mixture of 45 to 90% by weight of 1,6-hexanediol and 10 to 55% by weight of 2,2,4-trimethylpentanediol -1,3, first with a stoichiometric excess of an organic polyisocyanate followed by reaction with a chain extender which is preferably a diamine, hydrazine, a hydrazide or a glycol. If desired the reactions are carried out in the presence of an inert polar solvent such as dimethylformamide, dimethylacetamide, tetramethylurea or dimethyl sulphoxide. Up to 50% by weight of 2,2,4-trimethylpentanediol-1,3 may be replaced by 2,2-dimethylhexanediol-1,3. Suitable polyisocyanates are 4,4<SP>1</SP>-diphenylmethane diisocyanate; 2,4-toluylene diisocyanate; p-phenylene diisocyanate; 1,5-naphthylene diisocyanate; 1,6-hexane diisocyanate and 4,4<SP>1</SP>-diphenyl (thio) ether diisocyanates. The chain extenders may be ethylene diamine; propylene diamine; n-xylylene diamine; hydrazine; carbodihydrazide; adipodihydrazide; ethylene glycol and 1,4-butane diol. The resulting polymers may be used in the production of fibres or films. The preparation of polyesters from adipic acid and a diol mixture of 45 to 90% by weight of hexanediol-1,6 and 10 to 55% by weight of 2,2,4-trimethylpentanediol- 1,3 is described in the examples. In Example 1, the ratio of hexanediol-1,6 to 2,2,4-trimethylpentanediol-1,3 is 76À4: 23À6 and in Example 2 86À6: 13À4.
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