发明名称 TITANIUM-BASED CATALYST SHOWING EXCELLENT ACTIVITY AND SELECTIVITY IN POLYCONDENSATION REACTIONS
摘要 A polycondensation reaction mixture is disclosed which includes a catalyst, acyclic esters, ethylene glycol, and water. The catalyst is a titanium atrane. The polycondensation reaction mixture is prepared by the steps of (a) contacting a solution comprising a titanium (IV) alkoxide compound and a first solvent with an organic acid; (b) contacting the solution formed in step (a) with a substituted or unsubstituted trialkanolamine to form an impure catalyst; (c) purifying the impure catalyst to form the titanium atrane catalyst; and (d) bringing the catalyst into contact with the acyclic esters under conditions that produce the ethylene glycol and water.
申请公布号 US2014024798(A1) 申请公布日期 2014.01.23
申请号 US201313952438 申请日期 2013.07.26
申请人 EQUIPOLYMERS GMBH 发明人 WIEGNER JENS-PETER;VOERCKEL VOLKMAR;RUNKEL DIETMAR;ECKERT ROLF
分类号 C08G63/85 主分类号 C08G63/85
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