发明名称 |
SYNTHESIS OF THIOETHER CONTAINING TRIALKOXYSILANES |
摘要 |
The invention relates to a radical-initiated thiol-ene or thiol-yne "click" reaction that provides a simple and efficient route to diverse trialkoxysilanes. Trialkoxysilanes made in this way are obtained in quantitative to near-quantitative yields with high purity without any or minimal purification. A wide range of functional groups is tolerated in this approach, and even complex alkenes click with the silane precursors. The modular nature of these radical-based thiol-ene or thiol-yne "click" reactions allows a wide variety of pendant groups to be coupled to silane compounds that can then be coupled to a wide variety surfaces in order to modify their material properties. Consequently, such radical initiated thiol-ene and thiol-yne reactions provide facile and efficient methods for preparing an enormous number of surface-active functional trialkoxysilanes. |
申请公布号 |
US2013345412(A1) |
申请公布日期 |
2013.12.26 |
申请号 |
US201214001096 |
申请日期 |
2012.03.22 |
申请人 |
GARRELL ROBIN L.;TUCKER-SCHWARTZ ALEXANDER K.;THE REGENTS OF THE UNIVERSITY OF CALIFORNIA |
发明人 |
GARRELL ROBIN L.;TUCKER-SCHWARTZ ALEXANDER K. |
分类号 |
C07F7/18;C07F19/00 |
主分类号 |
C07F7/18 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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