发明名称 Hydrogenation of esters or carbonyl groups with tetradentate amino/imino-thioether based ruthenium complexes
摘要 The present invention relates to the field of catalytic hydrogenation and, more particularly, to the use of specific ruthenium catalysts, or pre-catalysts, in hydrogenation processes for the reduction of ketones and/or aldehydes into the corresponding alcohol respectively. Said catalysts are ruthenium complexes comprising a tetradentate ligand (L4) coordinating the ruthenium with: -two nitrogen atoms, each in the form of a primary or secondary amine (i.e. a NH2 or NH group) or N-alkyl imine functional groups (i.e. a C=N group), and -two sulfur atoms, each in the form of thioether functional groups.
申请公布号 US8614345(B2) 申请公布日期 2013.12.24
申请号 US201113996847 申请日期 2011.12.19
申请人 SANTORO FRANCESCO;SAUDAN LIONEL;SAUDAN MICHEL ALFRED JOSEPH;SAUDAN SYLVIA JOYEUSE ADELAIDE ADA;FIRMENICH SA 发明人 SANTORO FRANCESCO;SAUDAN LIONEL;SAUDAN CHRISTOPHE
分类号 C07F15/00;C07C29/141;C07C29/145;C07D317/54 主分类号 C07F15/00
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