发明名称 |
SELECTIVE OXIDATION OF HYDROCARBONS USING HETEROGENEOUS CATALYSTS |
摘要 |
A process for the complete or partial oxidation of hydrocarbons comprises contacting a C 1 -C 8 hydrocarbon and hydrogen peroxide in the presence of a heterogeneous catalyst under conditions suitable to convert the C 1 -C 8 hydrocarbon to at least one corresponding C 1 -C 8 oxygenate product, wherein the heterogeneous catalyst provides confinement and contains both Bronsted-Lowry and Lewis acid centers. Examples include zeolites modified with selected metals or metal oxides. Including copper, either in the catalyst, in a second catalyst of similar description, or as a homogeneous salt, increases both selectivity and activity of the process, particularly where an iron-containing catalyst is used. |
申请公布号 |
EP2671861(A1) |
申请公布日期 |
2013.12.11 |
申请号 |
EP20110715570 |
申请日期 |
2011.02.02 |
申请人 |
UNIVERSITY COLLEGE CARDIFF CONSULTANTS LIMITED |
发明人 |
HUTCHINGS, GRAHAM JOHN;LOPEZ-SANCHEZ, JOSE ANTONIO;HAMMOND, CERI;DIMITRATOS, NIKOLAOS;DUMMER, NICHOLAS F. |
分类号 |
C07C27/16 |
主分类号 |
C07C27/16 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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