POLYTHIOPHENE STAR COPOLYMER SELF-DOPED BY EXTERNAL STIMULI, PROCESS FOR PREPARATION OF THE SAME, CONDUCTIVE THIN FILM USING THE SAME AND METHOD FOR PREPARATION OF THE CONDUCTIVE THIN FILM

摘要

PURPOSE: A polythiophene star polymer copolymer capable of self doping by external stimulus is provided to steadily increase conductivity as a self-doping material, thereby being used for the material of a conductive thin film. CONSTITUTION: A manufacturing method of a polythiophene star polymer copolymer capable of self doping by external stimulus comprises: a step of forming a polythiophene macro initiator, a functional group capable of the polymerization of living radical is introduced at the terminus of polythiophene or the derivative; a step of forming a polymer macro initiator providing one or more dopants selected from sulfone group, carboxyl group, and phosphate group by external stimulus through living radical polymerization; and a step of polymerizing the polythiophene star polymer copolymer by adding the polymer macro initiator and at least one kind of divinyl monomer to the polythiophene macro initiator.