| 摘要 |
Disclosed herein are green-emitting, garnet-based phosphors having the formula (Lu1-a-b-cYaTbbAc)3(Al1-dBd)5(O1-eCe)12:Ce,Eu, where A is selected from the group consisting of Mg, Sr, Ca, and Ba; B is selected from the group consisting of Ga and In; C is selected from the group consisting of F, Cl, and Br; and 0@a@1; 0@b@1; 0<c@0.5; 0@d@1; and 0<e@0.2. These phosphors are distinguished from anything in the art by nature of their inclusion of both an alkaline earth and a halogen. Their peak emission wavelength may lie between about 500 nm and 540 nm; in one embodiment, the phosphor (Lu,Y,A)3Al5(O,F,Cl)12:Eu2+ has an emission at 540 nm. The FWHM of the emission peak lies between 80 nm and 150 nm. The present green garnet phosphors may be combined with a red-emitting, nitride-based phosphor such as CaAlSiN3 to produce white light.
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