发明名称 METHOD FOR PRODUCING ACRYLONITRILE
摘要 The present invention relates to a method for producing acrylonitrile, the method comprising a gas-phase catalytic ammoxidation step for obtaining acrylonitrile by bringing a starting gas comprising propylene, molecular oxygen, and ammonia into contact with a fluid bed catalyst and performing gas-phase catalytic ammoxidation. The method is characterized in that the fluid bed catalyst comprises particles containing Fe, Sb, and Te, and that the gas-phase catalytic ammoxidation step is performed while maintaining the B/A within a range of 2.0 to 5.0, where A is the Te/Sb atomic ratio in the bulk composition of the fluid bed catalyst and B is the Te/Sb atomic ratio in the surface composition of the particles of the fluid bed catalyst. By means of this method for producing acrylonitrile, long-term retention of a stable high acrylonitrile yield is possible.
申请公布号 WO2013129385(A1) 申请公布日期 2013.09.06
申请号 WO2013JP54944 申请日期 2013.02.26
申请人 MITSUBISHI RAYON CO., LTD. 发明人 KARASUDA TAKASHI;WATANABE HIROKAZU;YANAGITA MOTOO;NISHIDA KAZUFUMI
分类号 C07C253/26;B01J27/19;C07B61/00;C07C255/08 主分类号 C07C253/26
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