发明名称 METHOD OF PRODUCING MAGNESIA-ZIRCONIA MIXED CARRIER FOR CATALYST FOR OXIDATIVE DEHYDROGENATION OF N-BUTANE, METHOD OF PRODUCING MAGNESIUM-ZIRCONIA CARRIER-SUPPORTED MAGNESIUM ORTHOVANADATE CATALYST, AND METHOD OF PRODUCING N-BUTENE AND 1,3-BUTADIENE USING SAID CATALYST
摘要 PURPOSE: A method for preparing a magnesia-zirconia complex carrier is provided to simply obtain a magnesia-zirconia complex carrier for a normal-butane oxidative dehydrogenation catalyst which maintains the high activity of magnesium orthovanadate using a sol-gel method based on a citric acid. CONSTITUTION: A method for preparing a magnesia-zirconia complex carrier comprises the steps of: preparing a mixed precursor solution of magnesium and zirconium by dissolving a magnesium precursor and a zirconium precursor in a first solvent; preparing a solid acid solution by dissolving a solid acid into a second solvent; preparing a carrier forming solution by mixing the precursor solution and the solid acid solution; preparing a solid material by thermally drying the carrier forming solution at the temperature of 40-200°C; and preparing a magnesia-zirconia complex carrier by thermally treating the solid material at the temperature of 400-1000°C. A method for preparing a magnesium orthovanadate catalyst comprises the steps of: impregnating a vanadate aqueous solution into the magnesia-zirconia complex carrier; and thermally treating the resultant product at the temperature of 350-800°C for 1-6 hours. [Reference numerals] (AA) Yield of dehydrogenation products (%); (BB,DD) Sol-gel method; (CC.EE) Gel-oxalate method; (FF) Reaction time (h)
申请公布号 KR20130085709(A) 申请公布日期 2013.07.30
申请号 KR20120006693 申请日期 2012.01.20
申请人 SAMSUNG TOTAL PETROCHEMICALS CO., LTD. 发明人 YOO, YEON SHICK;CHO, YOUNG JIN;LEE, JIN SUK;CHANG, HO SIK;LEE, JONG KWON;LEE, HO WON;SONG, IN KYU
分类号 B01J21/10;B01J21/06;B01J38/02;C07C11/08 主分类号 B01J21/10
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