发明名称 |
METHODS FOR PREPARING RUTHENIUM CARBENE COMPLEX PRECURSORS AND RUTHENIUM CARBENE COMPLEXES |
摘要 |
A method for preparing a ruthenium carbene complex precursor includes reacting a ruthenium refinery salt with a hydrogen halide to form a ruthenium intermediate, and reacting the ruthenium intermediate with an L-type ligand to form the ruthenium carbene complex precursor. A method for preparing a ruthenium vinylcarbene complex includes converting a ruthenium carbene complex precursor into a ruthenium hydrido halide complex, and reacting the ruthenium hydrido halide complex with a propargyl halide to form the ruthenium carbene complex. A method for preparing a ruthenium carbene complex includes converting a ruthenium carbene complex precursor into a ruthenium carbene complex having a structure (PR1 R2R3)2CI2Ru=CH-R4, wherein R1, R2, R3, and R4 are alike or different, and wherein covalent bonds may optionally exist between two or more of R1, R2, and R3 and/or two of R1, R2, and R3 taken together may optionally form a ring with phosphorous. |
申请公布号 |
WO2013055644(A3) |
申请公布日期 |
2013.07.25 |
申请号 |
WO2012US59280 |
申请日期 |
2012.10.09 |
申请人 |
ELEVANCE RENEWABLE SCIENCES, INC.;KUNZ, LINDA, A.;COHEN, STEVEN, A.;LUETKENS, MELVIN, L. |
发明人 |
KUNZ, LINDA, A.;COHEN, STEVEN, A.;LUETKENS, MELVIN, L. |
分类号 |
C07F15/00 |
主分类号 |
C07F15/00 |
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