发明名称 Borohydride metallocene complex of a lanthanide, catalytic system including said complex, polymerization method using same and ethylene/butadiene copolymer obtained using said method
摘要 Borohydride metallocene complex of lanthanide, preparation process, catalytic system incorporating borohydride metallocene complex, process for copolymerization of olefins employing catalytic system. The complex corresponds to one or other of formulae A and B: where, in A, two ligands Cp1, Cp2, each composed of a cyclopentadienyl group, are connected to the lanthanide Ln, such as Nd, and where, in B, a ligand molecule, composed of two cyclopentadienyl groups Cp1, Cp2 connected to one another via a bridge P of formula MR1R2, M is an element from group IVa, and R1 and R2, which are identical or different, represent an alkyl group comprising from 1 to 20 carbon atoms, is connected to the lanthanide Ln, L is alkali metal, N is molecule of a complexing solvent, x is integral or non-integral number>=0, p is integer>=than 1 and y is integer>=0.
申请公布号 US8492573(B2) 申请公布日期 2013.07.23
申请号 US201113288130 申请日期 2011.11.03
申请人 THUILLIEZ JULIEN;BOISSON CHRISTOPHE;SPITZ ROGER;MICHELIN RECHERCHE ET TECHNIQUE S.A.;TOTAL PETROCHEMICALS FRANCE;CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE ECOLE SUPERIEURE DE CHIMIE-PHYSIQUE-ELECTRONIQUE 发明人 THUILLIEZ JULIEN;BOISSON CHRISTOPHE;SPITZ ROGER
分类号 C08F4/52;B01J31/22;C07F17/00 主分类号 C08F4/52
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