This invention provides processes for extracting organic compounds from aqueous samples by using relatively small amounts of extraction solvent and of the aqueous sample to be extracted. This is accomplished by increasing the surface area of the extraction solvent while preventing evaporation of the extraction solvent, which allows for greater extraction efficiency. There is little or no restriction on the aqueous sample types from which organic compounds can be extracted with the processes of this invention. An apparatus that can be employed in these processes is also provided.
