发明名称 |
MANUFACTURING METHOD FOR CARBON BASED MULTI-COMPOSITE METAL-OXIDE NANOCATALYSTS SUPPORT VIA MELT-INFILTRATION PROCESS AND CARBON BASED MULTI-COMPOSITE METAL-OXIDE NANOCATALYST SUPPORT THEREOF |
摘要 |
PURPOSE: A carbon based multi-composite metal oxide nano catalyst carrier and a production method thereof are provided to show high reactivity and high stability preventing coagulation between particles in case of a high-temperature catalytic reaction as active metal catalyst particles are uniformly carried onto a metal oxide and a remaining carbon carrier for scaffold in a high concentration. CONSTITUTION: A carbon based multi-composite metal oxide nano catalyst carrier production method comprises the following steps; a formation step which forms mixed powder by fusing metal-oxide salt-hydrate for a catalyst, metal-oxide salt-hydrate for a scaffold, and a porous carbon molding frame; a melt infiltration step which melts and impregnates the metal-oxide salt-hydrate for an active catalyst and the metal-oxide salt-hydrate for the scaffold into the carbon molding frame by melting and impregnating at a temperature around the melting point of the mixed metal-oxide salt-hydrate; a drying step which dries the mixed power which is melted and impregnated; and a removal and impregnating step which removes the carbon molding frame before sintering the mixed powder which is melted and impregnated at a high temperature, and impregnating the active metal-oxide particles into a metal oxide for the scaffold and remaining carbon by resolving the metal-oxide salt-hydrate for the active catalyst and the metal-oxide salt-hydrate for the scaffold. High temperature sintering is performed at a temperature ranged 300-650 deg. C for 1- 24 hours. [Reference numerals] (AA) Melt-infiltration; (BB) Amorphous salt complex dipped in porous carbon; (CC) High temperature sintering under the atmospheric condition; (DD) Removal of a carbon molding frame, Decomposition of salt; (EE) Oxidized metal particle(alumina, zirconia,..) functioning as a scaffold; (FF) Active particle; (GG) Remaining carbon |
申请公布号 |
KR101272210(B1) |
申请公布日期 |
2013.06.11 |
申请号 |
KR20120147508 |
申请日期 |
2012.12.17 |
申请人 |
KOREA INSTITUTE OF ENERGY RESEARCH |
发明人 |
PARK, JI CHAN;JUNG, HEON;LEE, HO TAE;YANG, JUNG IL;CHUN, DONG HYUN;HONG, SUNG JUN;KIM, TAE WAN |
分类号 |
B01J37/08;B01J37/02;C07F3/02 |
主分类号 |
B01J37/08 |
代理机构 |
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