发明名称 OPTICALLY ACTIVE BISOXAZOLINE COMPOUND, ASYMMETRIC CATALYST, AND METHOD FOR PRODUCING OPTICALLY ACTIVE CYCLOPROPANE COMPOUND USING THE CATALYST
摘要 <P>PROBLEM TO BE SOLVED: To solve the problem that, in conventional methods for producing an optically active cyclopropane compound, there are cases of being not always sufficiently satisfactory in terms of the selectivity of the compound's cis-trans isomers. <P>SOLUTION: An optically active bisoxazoline compound represented by formula (1) (wherein, R<SP POS="POST">1</SP>, R<SP POS="POST">2</SP>and R<SP POS="POST">3</SP>are each independently 1-8C alkyl, phenyl or benzyl; n is an integer of 0-3; and * denotes the asymmetric center) is provided. An asymmetric catalyst obtained by mixing the compound with a cuprous or cupric compound is also provided. <P>COPYRIGHT: (C)2013,JPO&INPIT
申请公布号 JP2013103904(A) 申请公布日期 2013.05.30
申请号 JP20110248357 申请日期 2011.11.14
申请人 SUMITOMO CHEMICAL CO LTD 发明人 MATSUMOTO TSUTOMU;MASUMOTO KATSUHISA;TANAKA AKIO
分类号 C07F7/18;B01J31/22;B01J31/30;C07B53/00;C07B61/00;C07C67/333;C07C69/757;C07C237/24;C07D263/14;C07D263/16 主分类号 C07F7/18
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