| 摘要 |
The invention relates to copper (I) complexes of the formula, where X* = Cl, Br, I, CN, OCN, SCN, alkinyl, and/or N3 and N*f1E = a bidentate ligand, wherein E = a phosphanyl/arsenyl/antimonyl group of the form R2E (in which R = alkyl, aryl, heteroaryl, alkoxyl, phenoxyl, or amid); N* = an imin function that is a component of an aromatic group selected from pyridyl, pyridazinyl, pyrimidyl, pyrazinyl, triazinyl, tetrazinyl, oxazolyl, thiazolyl, imidazolyl, pyrazolyl, isoxazolyl, isothiazolyl, 1,2,3-triazolyl, 1,2,4-triazolyl, 1,2,4-oxadiazolyl, 1,2,4-thiadiazolyl, tetrazolyl, 1,2,3,4-oxatriazolyl, 1,2,3,4-thiatriazolyl, chinolyl, isochinolyl, chinoxalyl, and chinazolyl, which are optionally additionally substituted and/or anneleated; and "f1" = at least one carbon atom that is likewise a component of the aromatic group, said carbon atom being found both directly adjacent to the amine nitrogen atom as well as to the phosphorous, arsenic, or antimony atom. The invention also relates to the use of said complexes in optoelectronic components. |
