发明名称 METHOD FOR SYNTHESIZING RARE EARTH METAL EXTRACTANT
摘要 A rare earth metal extractant containing, as the extractant component, dialkyldiglycol amide acid which is excellent in breaking down light rare earth elements is reacted in diglycolic acid (X mol) and an esterification agent (Y mol) at a reaction temperature of 70° C. or more and for a reaction time of one hour or more such that the mol ratio of Y/X is 2.5 or more, and is subjected to vacuum concentration. Subsequently, a reaction intermediate product is obtained by removing unreacted products and reaction residue. Then a nonpolar or low-polar solvent which is an organic solvent for forming an organic phase during solvent extraction of the rare earth metal and which is capable of dissolving dialkyldiglycol amide acid is added as the reaction solvent, and the reaction intermediate product is reacted with dialkyl amine (Z mol) such that the mol ratio of Z/X is 0.9 or more.
申请公布号 US2013123534(A1) 申请公布日期 2013.05.16
申请号 US201113808220 申请日期 2011.07.01
申请人 SAKAKI KAZUAKI;SUGAHARA HIROTO;KUME TETSUYA;OHASHI MASAKI;NAGANAWA HIROCHIKA;SHIMOJO KOJIRO;JAPAN ATOMIC ENERGY AGENCY;SHIN-ETSU CHEMICAL CO., LTD. 发明人 SAKAKI KAZUAKI;SUGAHARA HIROTO;KUME TETSUYA;OHASHI MASAKI;NAGANAWA HIROCHIKA;SHIMOJO KOJIRO
分类号 C07C231/02 主分类号 C07C231/02
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