Constructing superconducting carbon nano-tubes at room temperature by interior doping of their cavities with rod-shaped neutral or charged electrons, mesomeric structure and dipolar molecular structure easily adjustable at their ends

摘要

The method of constructing superconducting carbon nano-tubes (CNTs) at room temperature by interior doping of their cavities with rod-shaped neutral or charged electrons, mesomeric structure and dipolar molecular structure easily adjustable at their ends, is claimed, where a position of mesomeric molecular rods takes place along unsaturated molecular chains arrayed in the CNTs not by a chemical bond in a horizontal orientation to planar molecular strands, but via direct, vertical or tilted contact with an inner surface of the CNTs having a polarizable atom of the used dipole molecules. The method of constructing superconducting carbon nano-tubes (CNTs) at room temperature by interior doping of their cavities with rod-shaped neutral or charged electrons, mesomeric structure and dipolar molecular structure easily adjustable at their ends, is claimed, where a position of mesomeric molecular rods takes place along unsaturated molecular chains arrayed in the CNTs not by a chemical bond in a horizontal orientation to planar molecular strands, but via direct, vertical or tilted contact with an inner surface of the CNTs having a polarizable atom of the used dipole molecules that are not coordinated as single molecules to generate an optimal contact angle, as a radiation of star-shaped molecular structures, as ligand with acceptors to form metal atoms or as ligand with the acceptors to form molecular asterisk nuclear structures and as charged or neutral molecules that are radially aligned with the acceptors bridged by itself or linked to a given geometry. A diameter of the molecular structure is compatible with the cross-sectional area of the considered nanotube having an internal cavity that is filled with concentrated solution via diffusion by capillary action, to which the asterisks are configured to reach the maximum possible surface contacts of their radiation peaks with physical methods such as ionizing and others known methods. A solvent is removed by conventional methods and still remains between the CNTs, and the adhered asterisks are successively eluted by gentle washing with the solvents of different strength. Short, long or ultra-long, electrically uniform or defect-free single and multi-walled metallic CNTs have diameters. The ligands are chemically bonded to the molecular asterisk nuclear structure having the geometry such as neopentyl, and/or tetramethylmethane core, and are positively ionized by salt formation. Donor-acceptor substituted pi -systems are designed as dipolar molecular structures of conjugated oligomers, where the conjugated oligomers are terminated at their one end by an electron donor and other end by an electron acceptor and covalently bind to the acceptor and the molecular asterisk nuclear structure. Dyes such as diethyl-cyanine/iodide and structural analogues compounds are used as dipolar molecular structures, and are covalently bonded to the molecular asterisk nuclear structure. Resistant, rod-like color molecular structures are used as neutral color molecules. Dye classes are covalently attached at its one end by the strong electron donor and at its other end by the strong electron acceptor. A formation of an ideal color system is only possible for ions whose ionization occurs during bridging of the acceptors with the molecular asterisk core to form salts.