发明名称 Modified acidic ion-exchange resin and method for preparing bisphenol
摘要 The present invention provides an ion-exchange resin catalyst, as a catalyst for preparing bisphenol from phenol compounds and ketone, which has a higher selectivity to bisphenol and a longer life time, as compared to a conventional ion-exchange resin, and a method for preparing the same. The present invention also provides a method for preparing bisphenol comprising reacting phenol compounds with ketone, wherein the modified acidic ion-exchange resin in which at least one kind of cationic compound selected from the following (a), (b), (c) and (d) ionically binds to an acidic functional group, is used as a catalyst: (a) a quaternary phosphonium ion, (b) a quaternary ammonium ion, (c) a bis(phosphoranylidene) ammonium ion, and (d) an N-substituted nitrogen-containing aromatic cation.
申请公布号 US8436055(B2) 申请公布日期 2013.05.07
申请号 US20100875016 申请日期 2010.09.02
申请人 TERAJIMA TAKASHI;TAKAI TOSHIHIRO;FUJIWARA KENJI;MITSUI CHEMICALS, INC. 发明人 TERAJIMA TAKASHI;TAKAI TOSHIHIRO;FUJIWARA KENJI
分类号 B01J39/12;C08J5/20;B01J31/08;B01J39/08;B01J39/16;B01J39/20;C07B61/00;C07C37/20;C07C39/16 主分类号 B01J39/12
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