摘要 |
<p>The present invention relates to a process for water oxidation using a polyoxometalate compound of formula (I) as water oxidation catalyst. It is also related to some polyoxometalate compounds. Formula (I): [(M9(OH) 3(H20)6(HP04)2(L) 3][A] n wherein: M is selected from the group consisting of Co, Mn, and Fe; L is selected from the ligand of formula YM'9O34 and Upsilon2Mu15Omicron56; Y is selected from the group consisting of P, Si, Ge, and As; M' is selected from the group consisting of W, Mo, and V; A is a cation selected from the group consisting of Li+, Na+, K+, Rb+, Cs+, Ca2+, Ba2 +, Mg2+, and mixture thereof; and n is an integer selected from 8 and 16, being the sum of positive charges of An equal to 16.</p> |
申请人 |
FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA (ICIQ);INSTITUCIO CATALANA DE RECERCA I ESTUDIS AVANCATS |
发明人 |
GALAN, JOSE RAMON;LLOBET, ANTONI;GOBERNA FERRON, SARA;VIGARA RODRIGUEZ, LAURA;SORIANO LOPEZ, JOAQUIN |