摘要 |
In conventional Al coated steel sheet, with the Al coating as it is, black discoloration cannot be prevented at 550° C. or more. For this reason, post annealing is used to form a barrier layer and suppress the formation of Fe-Al intermetallic compounds. However, with this method, there were the problems that the steel sheet became poor in workability and, further, high temperature, long time heating was required, so there were problems from the workability, economy, and environmental aspect. The present invention provides steel sheet which has a heat black discoloration resistance even at a 550° C. or more high temperature without additional annealing after Al coating and further is excellent in workability. That is, it is hot dip Al coated steel sheet which comprises steel sheet which contains predetermined ingredients of C, Si, P, S, Al, N, and O plus one or both of furthermore Ni: 0.01 to 0.1% or Cu: 0.01 to 0.1% and satisfies 10×C+Ni+Cu>0.03 and an Al coating layer which contains Si: 4 to 11% on the surface of that steel sheet and which have a thickness 5 mum or less Al-Fe-Si alloy layer in the interface between the Al coating layer and the steel sheet. |