METHOD OF PRODUCING 1'-[2-(METHYLTHIO)ETHYL]- 1'-[S-ALKYLCARBOTHIOYL]-(C-I)[5,6]FULLERO[2',3':1,9]CYCLOPROPANES

摘要

FIELD: chemistry.SUBSTANCE: invention relates to organic synthesis, and specifically to a method of producing sulphur-containing fullerene derivatives of general formula (1):R=Am, i-Pr, Cy, Bn, which involves reaction of C-fullerene with diazothioates of formula N(CHCHSMe)C(O)SR (R = Am, i-Pr, Cy, Bn) in o-dichlorobenzene, taken in molar ratio C: diazo-compound = 0.01:(0.02-0.05), at temperature of 80°C for 0.5-1.5 hours.EFFECT: method of obtaining novel sulphur-containing fullerene derivatives, which can be used as effective nanocomponent additives for industrial oil, as well as novel optoelectronic materials.1 cl, 1 tbl