发明名称 |
AQUEOUS POLYTETRAFLUOROETHYLENE EMULSION AND PROCESS FOR PRODUCTION THEREOF, AQUEOUS POLYTETRAFLUOROETHYLENE DISPERSION OBTAINED USING THE EMULSION, POLYTETRAFLUOROETHYLENE FINE POWDER, AND STRETCH-EXPANDED BODY |
摘要 |
To produce a PTFE aqueous emulsion, whereby the environmental load is little, the stability of the aqueous emulsion is high, and a molded product having high heat resistance can be obtained. A process for producing a PTFE aqueous emulsion, which comprises emulsion-polymerizing tetrafluoroethylene (TFE) by means of at least one fluorinated emulsifier selected from the group consisting of a C 4-8 fluorinated carboxylic acid having from 1 to 4 etheric oxygen atoms in its main chain, and its salts, to obtain an aqueous emulsion containing polytetrafluoroethylene (PTFE) microparticles having an average primary particle size of from 0.1 to 0.3 µm, wherein at the beginning of the emulsion polymerization of TFE, a (polyfluoroalkyl)ethylene (a) represented by "CH 2 =CH-Rf 1 ", and/or a comonomer (b) having a monomer reactivity ratio r TFE of from 0.1 to 8 in copolymerization with tetrafluoroethylene, is incorporated to the emulsion polymerization system, so as to be from 0.001 to 0.01 mass% relative to the final amount of polytetrafluoroethylene produced. |
申请公布号 |
EP2500366(A4) |
申请公布日期 |
2013.04.03 |
申请号 |
EP20100828382 |
申请日期 |
2010.11.08 |
申请人 |
ASAHI GLASS COMPANY, LIMITED |
发明人 |
HIGUCHI, SHINYA;MATSUOKA, YASUHIKO;KOBAYASHI, SHIGEKI |
分类号 |
C08F214/26;C08F2/24;C08J9/00 |
主分类号 |
C08F214/26 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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