| 摘要 |
A porous substrate e.g. a cellulosic surface such as hardwoods, soft woods, particle boards, chipboards, hardboard and paper, is coated by first preheating the substrate to a temperature of at least 120 DEG F. to drive off air entrapped therein and then applying a solution containing a dissolved free-radical generating polymerization catalyst to the substrate to impregnate the surface of the substrate with the catalyst. Alternatively the impregnating with the catalyst may be carried out before the preheating. The impregnated and preheated substrate while still at an elevated temperature is coated with a liquid mixture comprising the reaction product of an ethylenically unsaturated dicarboxylic acid comprising at least 50% mol of fumaric acid, a glycol component comprising at least 50% mol of a polyoxyalkylene glycol having a molecular weight up to 1200 and a diene component comprising at least 50% mol of dicyclopentadiene such that there are provided 0.2 to 0.6 mol of dicyclopentadiene for each mol of dicarboxylic acid, the dicarboxylic acid and the glycol being employed in equivalent proportions of from 1.5:1 to 1:1.5 based on carboxyl and hydroxyl radicals respectively, and a copolymerizable ethylenically unsaturated monomer. The coated substrate is then heated at least partially to cure the coating. Other dicarboxylic acids, glycols and dienes are mentioned. Lists of copolymerizable monomers and free-radical generating catalysts are given. The coated substrate may be coated with another layer of the liquid polyester reaction product. In the examples Redwood boards were coated after preheating and treatment with methyl ethyl ketone peroxide in dibutyl phthalate with an unsaturated polyester formed from ethylene and diethylene glycols, fumaric acid and dicyclopentadiene, dissolved in styrene and containing p-tertiary-butyl catechol and cobalt naphthenate.ALSO:A porous substrate, e.g. a cellulosic surface such as hardwoods, soft woods, particle boards, chipboards, hardboard and paper, is coated by first preheating the substrate to a temperature of at least 120 DEG F. to drive off air trapped therein and then applying a solution containing a dissolved free-radical generating polymerization catalyst to the substrate to impregnate the surface of the substrate with the catalyst. Alternatively the impregnation may be carried out before the pre-heating. The impregnated and pre-heated substrate while still at an elevated temperature is coated with a liquid polyester mixture comprising the reaction product of an ethylenically unsaturated dicarboxylic comprising at least 59 mol per cent of fumaric acid, a glycol component comprising at least 50 mol per cent of a polyoxyalkylene glycol having a molecular weight up to 1200 and a diene component comprising at least 50 mol per cent of dicyclopentadiene such that there is present 0,2 -0,6 mol of dicyclopentadiene for each mol of dicarboxylic acid, the dicarboxylic acid and the glycol being in equivalent proportions of 1,5 : 1 to 1 : 1,5 based on carboxyl and hydroxyl groups respectively, and a copolymerizable ethylenically unsaturated monomer. The coated substrate is then heated at least partially to cure the coating. The coated substrate may be coated with another layer of the liquid polyester/copolymerizable monomer mixture. In the examples Redwood boards are pre-heated to a surface temperature of 140 DEG F. and then impregnated with a solution of methyl ethyl ketone peroxide catalyst in dibutyl phthalate using a roller coater, the surface temperature of the board now being 120 DEG F. The impregnated boards were then coated with a liquid polyester/styrene mixture using a curtain coater, the temperature of the boards now being 100 DEG F. The polyester-coated boards were allowed to stand for 1-2 minutes and then they were subjected to infra-red heating for four minutes to a maximum temperature of 180 DEG F. Alternatively the infra-red heating may be for two minutes only and the partially cured polyester coated boards recoated with the same polyester/styrene mixture. The polyester was formed from ethylene and diethylene glycols, fumaric acid and dicyclopentadiene. |
