| 摘要 |
Hydrocarbon diperchlorates are prepared by contacting certain kinds of feed reactants with perchloric acid in an emulsion comprising a strong sulfuric acid phase and an organic phase comprising an inert organic solvent. The feed reactants can be alkadienes, cycloalkadienes, diols of alkanes or cycloalkanes, and monools of alkenes or cycloalkenes, with certain restrictions on the proximity of the reactive positions. The perchloric acid can be generated in situ in the mixture by reaction of a perchlorate metal salt with the sulfuric acid. The hydrocarbon diperchlorate products have utility as detonatable sensitizers for explosives and as alkylating agents.
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