发明名称 PROCESS FOR THE PREPARATION OF PYRROLINES FROM GAMMA-NITROKETONES. USE OF THE GAMMA-NITROKETONES AS PESTICIDAL AGENTS.
摘要 <p>The invention is directed to method for the preparation of pyrrolines of the general formula (I) by catalytic hydration of a nitroketone of the general formula (II) employing a transition metal catalyst and gaseous hydrogen at an elevated pressure in a solvent, optionally in the presence of at least one additive selected among Lewis acids, Brønstedt acids, organic sulfur-containing compounds, organic or inorganic bases, and water scavengers, wherein in formulae (I) and (II) B<sup>1</sup>, B<sup>2</sup>, B<sup>3</sup>, B<sup>4</sup>, X, R, and T are as defined in the specification, and to a nitroketone of formula (II) to be used as intermediate in the process according to the invention and as pesticidal agent.</p>
申请公布号 MX2012011857(A) 申请公布日期 2013.02.07
申请号 MX20120011857 申请日期 2011.04.11
申请人 BAYER INTELLECTUAL PROPERTY GMBH 发明人 SHIBUYA, KATSUHIKO;SHIMOJO, EIICHI;ICHIHARA, TERUYUKI;HATAZAWA, MAMORU;ATAKA, MASASHI;MORADI, AHMED WAHED;MUELLER, THOMAS NORBERT;MURATA, TESUYA;BRUECHNER, PETER;GOERGENS, ULRICH
分类号 C07D207/18;A01N37/18;A01N43/653;C07C233/31;C07C233/33;C07D249/08 主分类号 C07D207/18
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