发明名称 PRODUCTION OF ETHYLENICALLY UNSATURATED CARBOXYLIC ACID SALTS BY THE CARBOXYLATION OF ALKENES
摘要 The invention relates to a method for producing an alkali or earth alkali salt of an a,ß-ethylenically unsaturated carboxylic acid, wherein a) an alkene, carbon dioxide and a carboxylation catalyst is reacted to form an alkene/carbon dioxide/carboxylation catalyst adduct, b) using an auxiliary base, the adduct is decomposed into the auxiliary base salt of the a,ß-ethylenically unsaturated carboxylic acid releasing the carboxylation catalyst, c) using an alkali or earth alkali metal base, the auxiliary base salt of the a,ß-ethylenically unsaturated carboxylic acid is reacted to form the alkali or earth alkali salt of the a,ß-ethylenically unsaturated carboxylic acid releasing the auxiliary base. Salts of a,ß-ethylenically unsaturated carboxylic acids, such as in particular sodium acrylate, are required in large quantities, for example, for producing water-absorbing resins.
申请公布号 EP2542516(A2) 申请公布日期 2013.01.09
申请号 EP20110706270 申请日期 2011.03.03
申请人 BASF SE 发明人 LIMBACH, MICHAEL;MILLER, JEREMIE;SCHUNK, STEPHAN
分类号 C07B41/08;C07B41/10;C07C51/15;C07C51/41;C07C57/04;C07C57/08;C07C57/10 主分类号 C07B41/08
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