| 摘要 |
The invention described the highly conducting amorphous polymer materials which are based on the pure block-type copolymers, which contain polyethylene oxide and other chemically complementary blocks and form the amorphous hydrogen-bonded intramolecular polycomplexes, and those, filled by ion conductive materials, low-molecular-weight organic plasticizer and nanometer-scale inorganic particles. The block-type copolymers are preferably the linear triblock copolymers with a central block of PEO and two side blocks of chemically complementary polyacrylamide (PAAm) or poly(acrylic acid) (PAAc). Due to existence of long side PAAm chains and their interaction with a central crystallizable block of PEO, TBC bulk structure is amorphous and fully homogeneous. It can be represented as a totality of hydrogen-bonded segments of both polymer components, uniformly distributed in PAAm matrix. Presented polymer materials can be used for solid polymer electrolyte for DSSC solar cells and lithium batteries. |
