发明名称 |
IRON-BASED FISHCER-TROPSCH CATALYST WITH HIGH CATALYTIC ACTIVITY AND OLEFIN SELECTIVITY, PREPARATION METHOD THEREOF, AND METHOD FOR PREPARING HEAVY OLEFIN USING THE SAME |
摘要 |
PURPOSE: An iron-based Fischer-tropsch catalyst with high catalytic activity and olefin selectivity, a preparation method thereof, and a reparation method of light olefin using syngas using the catalyst are provided to increase the life stability of the catalyst by reducing the occurrence of catalyst cracking phenomenon. CONSTITUTION: An iron-based catalyst for a Fischer-tropsch reaction includes potassium, iron, copper, manganese, and aluminum or silicon at the molar ratio of 1 to 6:100:1 to 6:1 to 20:5 to 40. The preparation method of the catalyst includes the following: acidic or neutral precursor compounds of the metals are dissolved in distilled water to prepare an acidic catalytic precursor solution; a basic precipitate is dissolved in distilled water to prepare a basic precipitating solution; the acid catalytic precursor solution is mixed with the basic precipitating solution, and the mixture is co-precipitated to obtain catalytic precursor slurry; the catalytic precursor slurry is aged to obtain a catalytic precursor precipitate; the precipitate is treated to obtain catalytic oxide; and a potassium compound aqueous solution is carried in the catalytic oxide, and the resultant product is dried and plasticized. |
申请公布号 |
KR20120108323(A) |
申请公布日期 |
2012.10.05 |
申请号 |
KR20110026024 |
申请日期 |
2011.03.23 |
申请人 |
SAMSUNG TOTAL PETROCHEMICALS CO., LTD.;KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY |
发明人 |
KIM, WON YOUNG;CHANG, HO SIK;LEE, JIN SUK;KIM, JEONG RANG;JUN, KI WON;LEE, YUN JO;PARK, JO YONG |
分类号 |
B01J23/889;B01J29/40;B01J37/02;C07C1/04 |
主分类号 |
B01J23/889 |
代理机构 |
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